Product ID:MIL-C-46168D PART B, 4 TO 1 BLEND
MSDS Date:04/04/1990
FSC:8010
NIIN:01-144-9873
Kit Part:Y
MSDS Number: BNTQW

NILES CHEMICAL PAINT CO

225 FORT STREET
NILES, MI 49120
US

Emergency Phone: 219-236-5856

Info Phone: 616-683-3377

Preparer: MICHAEL J LICHATOWICH

Cage: 02388

NILES CHEMICAL PAINT

307 NILES, MI 49120 US

Telephone: 616-683-3377/219-236-5856

Cage: 02388

HOMOPOLYMER OF HDI (VAPOR PRESSURE 7.5E-5 MM @ 20 C)

CAS: 28182-81-2

RTECS: NQ9170000

Fraction By Weight: 75%

HEXAMETHYLENE DIISOCYANATE

CAS: 822-06-0

RTECS: MO1740000

Fraction By Weight: #

ACGIH TLV: 0.005 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

# RESIDUAL MONOMER CONTENT LESS THAN 0.5% BASED ON RESIN

RTECS: 9999999ZZ

## CONTENT MAY RISE TO MAXIMUM OF 1.6%. MANUFACTURER ALSO

RTECS: 9999999ZZ

XYLENE (VAPOR PRESSURE 7.0 MM @ 20 C)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 12.5%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/150 PPM STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

N-BUTYL ACETATE (SARA III) (VAPOR PRESSURE 10 MM @ 20 C)

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 12.5%

OSHA PEL 150 PPM

ACGIH TLV: 150 PPM/200 PPM STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

2.21 LBS/GL

RTECS: 9999999VO

LD50 LC50 Mixture:ORAL LD50: 4,300 MG/KG (RATS). **
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL: MUCOUS MEMBRANE/RESP TRACT
IRRIT. BRONCHITIS/BRON SPASM, PULMONARY EDEMA. CHEM/HYPERSENSITIVE
PNEUMONITIS. NOSE/THROAT/EYE IRRIT. IMMED DANGEROUS TO LIFE/HLTH.
ISOCYANATE SENSITIZATION (CHEM AS THMA). NON-SPECIFIC ASTHMATIC
RESPONSE.LUNG DAMAGE/REDUCED FUNCTION. PERM BRAIN/NERV SYS DAMAGE.
NEUROTOXIC EFFECTS.***
Explanation of Carcinogenicity:NOT LISTED BY NTP, IARC OR OSHA.
**INHAL LC50: 137 TO 1150 MG/M3 (RAT). MORE INFO ON FILE.
Effects of Overexposure:INHAL: RUNNY NOSE, SORE THROAT, COUGH, CHEST
DISCOMFORT, SHORT BREATH, BREATH OBSTRUCT. FLU-LIKE SYMPTOM. DRY
THROAT, TIGHT CHEST. HEADACHE, NAUSEA, NARCOSIS, FATIGUE, APPETITE
LOSS, WHEEZE, ASTHMATIC ATTACK. INTELLECT/COORDINATN LOSS. SKIN:
RED, SWELL, RASH, SCALING, BLISTER. DRY, CRACK SKIN. INFECTION
SUSCEPTIBLE.#
Medical Cond Aggravated by Exposure:ASTHMA AND OTHER RESPIRATORY
DISORDERS (BRONCHITIS, EMPHYSEMA, HYPERREACTIVITY), SKIN ALLERGIES,
ECZEMA.

First Aid:INHAL: MOVE TO FRESH AIR. ADMIN OXYGEN/ARTIF RESP AS NEEDED.
GET MED AID. ASTHMATIC SYMPTOM MAY DEVELOP, TREAT SYMPTOMS. SEE DR.
SKIN: REMOVE CONTAM CLOTH IMMED. WASH W/SOAP & WTR. WASH CONTAM
CLOTH B EFORE REUSE. SEVERE EXPOS, GET UNDER SFTY SHOWER AFTER
REMOVING CLOTH. GET MED AID. LESSER EXPOS, GET MED AID IF IRRIT
DEVELOPS. EYE: FLUSH W/LUKEWARM WATER (LOW PRESSURE) 15 MIN,
LIFTING EYELIDS.##

Flash Point Method:SCC
Flash Point:91.0F,32.8C
Lower Limits:1.0
Upper Limits:7.6
Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL.
Fire Fighting Procedures:EMERG EQUIP W/SCBA & PROTECT CLOTH. HDI
VAPOR/TOXIC GASES GENERATED. KEEP FROM HEAT/IGNIT SOURCE. CLSD
CNTNR EXPLOD W/HEAT/CONTAM W/WTR. VAPOR HEAVY, TRAVEL *
Unusual Fire/Explosion Hazard:N/K * TO IGNITION SOURCE AND
FLASH BACK.

Spill Release Procedures:EVAC NONESSENTIAL. REMOVE IGNIT SOURCES. VENT
AREA. DIKE. NOTIFY AUTHORITIES. COVER W/SAWDUST, VERMIC, FULLER'S
EARTH, ETC. POUR DECONTAM SOLUTION OVER SPILL, ALLOW TO REACT 10
MIN. COLLECT IN OPEN CN TNRS, COVER LOOSELY. LET STAND 24-48 HRS.
Neutralizing Agent:TERGITOL TMN-10 (20%)/WATER (80%); CONC AMMONIA
(3-8%)/DETERG (2%)/WTR (90-95%)

Handling and Storage Precautions:-30F TO 122F STORAGE TEMP. AVERAGE
SHELF LIFE: 12 MO @ 77F. KEEP FROM HEAT/IGNIT SOURCES. GRND CNTNR
DURING STOR/TRANSFER. STORE IN CLSD CNTNR.
Other Precautions:DON'T RESEAL IF CONTAM SUSPECTED. AT MAX STOR TEMP,
MAT'L MAY SLOWLY POLYMERIZE W/OUT HAZARD. IDEAL STOR TEMP 50-81F.
AVOID SKIN/EYE CONTACT. EMPLOYEE EDUCATION/TRAINING-SAFE
USE/HANDLING PRODUCT REQU IRED.

Respiratory Protection:RSPRTR APPROVED FOR ISOCYANATE CONTAINING
ENVIRNMNTS (AIR PURIFYING/FRESH AIR SUPPLIED) MAY BE NECESSARY.
CONSIDER TYPE OF APPLICATION & ENVIRONMENTAL CONC. OBSERVE OSHA
REGULATIONS FOR RESPIRATORY US E (29 CFR 1910.134). MORE INFO ON
FILE.
Ventilation:PROVIDE SUFF EXHAUST VENT TO KEEP CONC OF
HDI/POLYISOCYANATE BELOW TLV/MGL. EXHAUST MAY NEED TO BE CLEANED.
Protective Gloves:CHEMICAL RESISTANT GLOVES: NITRILE/VITON
Eye Protection:SFTY GLASSES, SPLSH GOGGLES, FACE SHIELD
Other Protective Equipment:COVER EXPOSED SKIN. IF CREAM USED KEEP AREA
ONLY COVERED BY CREAM TO MINIMUM. USE SFTY SHOWERS & EYEWASH
STATIONS.
Work Hygienic Practices:DON'T WEAR CONTACT LENSES. DON'T BREATH VAPOR.
AVOID SKIN/EYE CONTACT. IN SPRAY OPS, PROTECT AGAINST EXPOS TO
PROD.
Supplemental Safety and Health
***EYE: TEAR/RED/SWELLING W/STING. #ACTION IN DIGESTIVE
TRACT. VOMITING MAY CAUSE ASPIRATION OF SOLVENT RESULTING IN CHEM
PNEUMONITIS. ## GET TO DR/OPTHAMALOGIST IMMED. INGE ST:
DON'T INDUCE VOMIT. DRINK 1-2 CUPS MILK/WATER. NOTHING BY MOUTH TO
UNCONSCIOUS/CONVULSING PERSON. MORE INFO ON FILE.

Vapor Density:> AIR
Spec Gravity:8.85 LBS/GAL
Viscosity:183 MPAS @20C
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:INSOLUBL/REACT W/WTR
Appearance and Odor:CLEAR TO PALE YELLOW LIQUID/SOLVENT ODOR.
Percent Volatiles by Volume:CA 30

Stability Indicator/Materials to Avoid:YES
WATER, AMINES, STRONG BASES, ALCOHOLS, METAL COMPOUNDS AND SURFACE
ACTIVE MATERIALS.
Stability Condition to Avoid:MOISTURE, HIGH TEMPERATURES, SHOCK FROM
DROPPING.
Hazardous Decomposition Products:BY HIGH HEAT & FIRE: CARBON DIOXIDE,
CARBON MONOXIDE, OXIDES OF NITROGEN, TRACES OF HCN & HDI.
Conditions to Avoid Polymerization:MAY OCCUR IF IN CONTACT WITH
MOISTURE OR OTHER MATERIALS WHICH REACT W/ISOCYANATES. MAY OCCUR AT
TEMPS ABOVE 400F.

Waste Disposal Methods:WASTE MUST BE DISPOSED OF IN ACCORDANCE W/FED,
STATE & LOCAL REGS. INCINERATION PREFERRED. EMPTY CNTNR MUST BE
HANDLE W/CARE. DECONTAM CNTNRS PRIOR TO DISPOSAL. DON'T HEAT/CUT
ON/NEAR EMPTY CNTNRS W/E LECTRICAL OR GAS TORCH. RCRA
IGNITABLE;D001.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.